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Table 4 The pH, total and ammonium nitrogen, as well as the amounts of acids in fresh and ensiled hemp, maize and faba bean

From: Evaluation of preservation methods for improving biogas production and enzymatic conversion yields of annual crops

Crop, year and treatment

Months

pH

NH3, g/kg

Percentage of dry matter

    

Total N

Oxalic acid

Formic acid

Malic acid

Lactic acid

Acetic acid

VFA

Hemp 2008:

          

Fresh

0

8.0

0.6

1.2

0.6

ND

1.3

ND

0.3

ND

No additives

4

5.5

0.6

1.2

ND

ND

1.8

7.8

1.7

0.6

 

8

6.4

1.8

1.3

ND

ND

2.5

7.3

2.2

0.6

Formic acid

4

4.2

0.6

1.3

1.2

4.3

2.1

ND

0.9

0.4

 

8

4.3

0.7

1.3

0.8

3.3

1.9

1.4

1.0

0.5

Hemp 2009:

          

Fresh

0

7.0

ND

1.1

4.9

ND

0.7

ND

1.2

ND

No additives

4

7.5

1.1

1.1

3.0

ND

2.7

2.2

1.0

0.4

 

8

8.1

0.9

1.0

2.7

ND

1.2

0.5

0.7

0.4

Urea

4

8.6

14.3

1.5

5.7

ND

0.8

ND

2.1

0.4

 

8

8.7

8.4

1.6

5.1

ND

0.9

ND

2.1

0.4

Maize 2008:

          

Fresh

0

5.5

0.3

1.7

9.2

ND

2.0

ND

ND

1.0

No additives

4

4.3

0.7

1.7

9.6

0.9

0.7

8.2

3.0

1.2

 

8

4.2

0.8

1.6

9.0

0.9

0.8

7.5

2.9

1.2

Formic acid

4

3.7

0.1

1.7

9.9

3.6

2.1

ND

ND

1.6

 

8

3.7

ND

1.7

6.8

2.4

1.4

ND

ND

0.4

Faba bean 2008:

          

Fresh

0

5.6

ND

3.0

0.1

ND

2.3

ND

0.7

1.1

No additives

4

4.6

0.8

3.0

0.1

ND

2.5

8.2

2.3

0.5

 

8

4.6

1.4

3.0

0.1

ND

2.7

8.8

2.3

0.5

Formic acid

4

4.2

0.5

3.1

0.2

3.7

3.2

2.1

0.9

0.7

 

8

4.1

1.4

3.1

0.4

4.0

3.6

2.7

1.0

0.6

  1. Acids and NH3 were determined from the filtrates of the blended crops.
  2. aPrewilted for urea ensiling.
  3. bExpressed as % of dry matter.
  4. ND = not detected; VFA = volatile fatty acids (propionic, butyric, valeric and isovaleric).