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Table 5 Gas chromatography-mass spectroscopy analysis of bio-oil products of duckweed, azolla and microalgae pyrolysis

From: Dual application of duckweed and azolla plants for wastewater treatment and renewable fuels and petrochemicals production

Retention time, minutes

Duckweed

Azolla (green)

Azolla (red)

Microalgae

4.3

  

Toluene

Toluene

4.9

  

3-Methyl furan and/or 3-Cyclopenten-1,2 diol

 

5.2

  

Tetrahydro-4H-pyran-4-ol

 

5.5

  

4-Cyclohexene-1,2-diol

 

5.58

   

2-Methyl-1H-Pyrrole

5.72

 

2,4,5-Trimethyl 1H-imidazole

  

5.8

  

1,2-Diemthyl-2-pyrroline

 

6.18

   

Piperidine

6.33

 

Phenol

Phenol

Phenol

6.72

2,3-Dimethyl-1H-Pyrrole

  

2,3-Dimethyl-1H-Pyrrole

6.83

   

4-Ethyl-2-methyl-1H- pyrrole

7.38

2-Methyl phenol

2-Methyl phenol

2-Methyl phenol

 

7.9

3-Methyl phenol

3-Methyl phenol

3-Methyl phenol

 

8.3

   

3-Ethyl-2,5-dimethyl-1H-pyrrole

8.38

   

3-Ethyl-2,4-dimethyl-1H-pyrrole

8.77

4-Methyl phenol

   

9.28

  

Dodecane

 

9.33

   

2-Isopropylpyrazine

9.43

   

3-Ethyl-2,4,5-Trimethyl-1H-Pyrrole

9.67

4-Ethyl phenol

   

10.13

2-Ethyl phenol

   

10.67

 

Tridecane

Tridecane

 

10.83

   

Indole

11.77

Indolizine

Indolizine

Indolizine

 

11.98

 

Tetradecane

Tetradecane

Tetradecane

12.83

3-Methyl Indolizine

  

3-Methyl Indolizine

13.23

 

Pentadecane

Pentadecane

Pentadecane

13.37

4-Methyl 1H-indole

   

14.43

 

Hexadecane

Hexadecane

Hexadecane

15.28

   

6,9-Heptadecadiene

15.37

   

1,15-Pentadecanediol

15.38

   

8-Heptadecane

15.57

 

Heptadecane

Heptadecane

Heptadecane

15.93

3,7,11,15-Tetramethyl-2-hexadecene

3,7,11,15-Tetramethyl-2-hexadecene

3,7,11,15-Tetramethyl-2-hexadecene

3,7,11,15-Tetramethyl-2-hexadecene

16.65

 

Octadecane

Octadecane

 

17.1 to 17.55

Isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol)

Various isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol)

Various isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol)

Various isomers of 3,7,11,15-Tetramethyl-2-hexadecen-1-ol (phytol)

17.8

   

Nonadecane

18.25

 

Palmitoleic acid

Palmitoleic acid

 

18.65

 

Eicosane (C20)

  

19.58

 

Heneicosane (C21)

  

19.75

   

Linolenic acid