Method | SEL calibration1,a | RMSEC2,a | RM- SECV3,a | R2Cal4 | R2CV5 | F6 | Outliers7 |
---|---|---|---|---|---|---|---|
Raman 2 nd deriv (19 pt) + SNV 32 scans | 0.05 | 0.13 | 0.14 | 0.83 ± 0.02 | 0.81 ± 0.02 | 4-5 | 2 |
Raman 1 st deriv (7 pt) + EMSC 32 scans | 0.05 | 0.13 | 0.14 | 0.845 ± 0.003 | 0.82 ± 0.01 | 4-5 | 3 |
Raman EMSC + 2 nd deriv (15 pt) 96 scans | 0.05 | 0.13 | 0.14 | 0.83 ± 0.01 | 0.81 ± 0.01 | 5-6 | 2-3 |
Raman 2 nd deriv (15 pt) + SNV 96 scans | 0.05 | 0.13 | 0.13 | 0.84 ± 0.01 | 0.82 ± 0.01 | 4-5 | 4-5 |
MIR EMSC + 2 nd deriv (15 pt) | 0.05 | 0.13 | 0.14 | 0.84 ± 0.03 | 0.81 ± 0.03 | 3-4 | 1-2 |
MIR 2 nd deriv (17 pt) + MSC | 0.05 | 0.13 | 0.14 | 0.82 ± 0.01 | 0.78 ± 0.01 | 3-4 | 1-2 |
MIR 2 nd deriv (17 pt) + SNV | 0.05 | 0.13 | 0.14 | 0.85 ± 0.02 | 0.82 ± 0.03 | 3-4 | 2-3 |
NIR EMSC + 2 nd deriv (25 pt) | 0.05 | 0.17 | 0.18 | 0.73 ± 0.01 | 0.681 ± 0.004 | 4-5 | 4-7 |
NIR 2 nd deriv (25 pt) + MSC | 0.05 | 0.17 | 0.18 | 0.72 ± 0.02 | 0.68 ± 0.02 | 4-6 | 1-5 |
NIR 2 nd deriv (25 pt) + SNV | 0.05 | 0.16 | 0.17 | 0.74 ± 0.01 | 0.70 ± 0.02 | 4-5 | 2-3 |