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Table 1 Poly[(R)-3-hydroxybutyric acid] vibrational modes and spectral assignments

From: Localization of polyhydroxybutyrate in sugarcane using Fourier-transform infrared microspectroscopy and multivariate imaging

Vibrational mode (cm−1)

Spectral assignment

979

C=C [31]

1045

C–CH3 stretching [32]

1056

C–O stretching [32]

1101

C–O–C stretching [32]

1131

CH3 rocking [32]

1182

C–O–C stretching [32, 33]

1228

C–O–C stretching [32, 33], CH2 wagging [31]

1262

C–O–C stretching + CH deformation [32, 33]

1271

C–O–C stretching (amorphous) [32]

1280

C–O–C stretching (crystalline) [32, 33]

1290

CH deformation [32]

1356

CH deformation and CH3 symmetric deformation [32]

1378

CH3 symmetric deformation [32]

1456

CH2 scissoring, CH3 asymmetric deformation [32]

1720

C=O stretch (crystalline) [32–34]

1747

C=O stretch (amorphous) [32, 34]