TY - JOUR AU - Ragauskas, A. J. AU - Williams, C. K. AU - Davison, B. H. AU - Britovsek, G. AU - Cairney, J. AU - Eckert, C. A. AU - Frederick, W. J. AU - Hallett, J. P. AU - Leak, D. J. AU - Liotta, C. L. PY - 2006 DA - 2006// TI - The path forward for biofuels and biomaterials JO - Science VL - 311 UR - https://doi.org/10.1126/science.1114736 DO - 10.1126/science.1114736 ID - Ragauskas2006 ER - TY - JOUR AU - Ragauskas, A. J. AU - Beckham, G. T. AU - Biddy, M. J. AU - Chandra, R. AU - Chen, F. AU - Davis, M. F. AU - Davison, B. H. AU - Dixon, R. A. AU - Gilna, P. AU - Keller, M. PY - 2014 DA - 2014// TI - Lignin valorization: improving lignin processing in the biorefinery JO - Science VL - 344 UR - https://doi.org/10.1126/science.1246843 DO - 10.1126/science.1246843 ID - Ragauskas2014 ER - TY - JOUR AU - McCann, M. C. AU - Carpita, N. C. PY - 2015 DA - 2015// TI - Biomass recalcitrance: a multi-scale, multi-factor and conversion-specific property JO - J Exp Bot VL - 66 UR - https://doi.org/10.1093/jxb/erv267 DO - 10.1093/jxb/erv267 ID - McCann2015 ER - TY - JOUR AU - Himmel, M. E. AU - Ding, S. -. Y. AU - Johnson, D. K. AU - Adney, W. S. AU - Nimlos, M. R. AU - Brady, J. W. AU - Foust, T. D. PY - 2007 DA - 2007// TI - Biomass recalcitrance: engineering plants and enzymes for biofuels production JO - Science VL - 315 UR - https://doi.org/10.1126/science.1137016 DO - 10.1126/science.1137016 ID - Himmel2007 ER - TY - JOUR AU - Li, M. AU - Pu, Y. AU - Ragauskas, A. J. PY - 2016 DA - 2016// TI - Current understanding of the correlation of lignin structure with biomass recalcitrance JO - Front Chem VL - 4 UR - https://doi.org/10.3389/fchem.2016.00045 DO - 10.3389/fchem.2016.00045 ID - Li2016 ER - TY - JOUR AU - Yan, L. AU - Ma, R. AU - Li, L. AU - Fu, J. PY - 2016 DA - 2016// TI - Hot water pretreatment of lignocellulosic biomass: an effective and environmentally friendly approach to enhance biofuel production JO - Chem Eng Technol VL - 39 UR - https://doi.org/10.1002/ceat.201600394 DO - 10.1002/ceat.201600394 ID - Yan2016 ER - TY - JOUR AU - Zhuang, X. AU - Wang, W. AU - Yu, Q. AU - Qi, W. AU - Wang, Q. AU - Tan, X. AU - Zhou, G. AU - Yuan, Z. PY - 2016 DA - 2016// TI - Liquid hot water pretreatment of lignocellulosic biomass for bioethanol production accompanying with high valuable products JO - Bioresour Technol VL - 199 UR - https://doi.org/10.1016/j.biortech.2015.08.051 DO - 10.1016/j.biortech.2015.08.051 ID - Zhuang2016 ER - TY - JOUR AU - Kim, Y. AU - Hendrickson, R. AU - Mosier, N. S. AU - Ladisch, M. R. PY - 2009 DA - 2009// TI - Liquid hot water pretreatment of cellulosic biomass JO - Biofuels Methods Protoc VL - 581 ID - Kim2009 ER - TY - STD TI - Mosier NS. Fundamentals of aqueous pretreatment of biomass. Aqueous pretreatment of plant biomass for biological and chemical conversion to fuels and chemicals. Wiley: New Jersey; 2013. pp. 129–143. ID - ref9 ER - TY - JOUR AU - Nitsos, C. K. AU - Choli-Papadopoulou, T. AU - Matis, K. A. AU - Triantafyllidis, K. S. PY - 2016 DA - 2016// TI - Optimization of hydrothermal pretreatment of hardwood and softwood lignocellulosic residues for selective hemicellulose recovery and improved cellulose enzymatic hydrolysis JO - ACS Sustain Chem Eng VL - 4 UR - https://doi.org/10.1021/acssuschemeng.6b00535 DO - 10.1021/acssuschemeng.6b00535 ID - Nitsos2016 ER - TY - JOUR AU - Grénman, H. AU - Eränen, K. AU - Krogell, J. AU - Willför, S. AU - Salmi, T. AU - Murzin, D. Y. PY - 2011 DA - 2011// TI - Kinetics of aqueous extraction of hemicelluloses from spruce in an intensified reactor system JO - Ind Eng Chem Res VL - 50 UR - https://doi.org/10.1021/ie101946c DO - 10.1021/ie101946c ID - Grénman2011 ER - TY - JOUR AU - Mok, W. S. L. AU - Antal, M. J. PY - 1992 DA - 1992// TI - Uncatalyzed solvolysis of whole biomass hemicellulose by hot compressed liquid water JO - Ind Eng Chem Res VL - 31 UR - https://doi.org/10.1021/ie00004a026 DO - 10.1021/ie00004a026 ID - Mok1992 ER - TY - JOUR AU - Kumar, R. AU - Mago, G. AU - Balan, V. AU - Wyman, C. E. PY - 2009 DA - 2009// TI - Physical and chemical characterizations of corn stover and poplar solids resulting from leading pretreatment technologies JO - Bioresour Technol VL - 100 UR - https://doi.org/10.1016/j.biortech.2009.01.075 DO - 10.1016/j.biortech.2009.01.075 ID - Kumar2009 ER - TY - STD TI - Liu C, Wyman CE. Impact of fluid velocity on hot water only pretreatment of corn stover in a flow through reactor. In: Proceedings of the Twenty-Fifth Symposium on Biotechnology for Fuels and Chemicals Held May 4–7, 2003, in Breckenridge, CO: 2004. Springer: 977–987. ID - ref14 ER - TY - JOUR AU - Donohoe, B. S. AU - Decker, S. R. AU - Tucker, M. P. AU - Himmel, M. E. AU - Vinzant, T. B. PY - 2008 DA - 2008// TI - Visualizing lignin coalescence and migration through maize cell walls following thermochemical pretreatment JO - Biotechnol Bioeng VL - 101 UR - https://doi.org/10.1002/bit.21959 DO - 10.1002/bit.21959 ID - Donohoe2008 ER - TY - JOUR AU - Ko, J. K. AU - Kim, Y. AU - Ximenes, E. AU - Ladisch, M. R. PY - 2015 DA - 2015// TI - Effect of liquid hot water pretreatment severity on properties of hardwood lignin and enzymatic hydrolysis of cellulose JO - Biotechnol Bioeng VL - 112 UR - https://doi.org/10.1002/bit.25349 DO - 10.1002/bit.25349 ID - Ko2015 ER - TY - JOUR AU - Pu, Y. AU - Hu, F. AU - Huang, F. AU - Davison, B. H. AU - Ragauskas, A. J. PY - 2013 DA - 2013// TI - Assessing the molecular structure basis for biomass recalcitrance during dilute acid and hydrothermal pretreatments JO - Biotechnol Biofuels VL - 6 UR - https://doi.org/10.1186/1754-6834-6-15 DO - 10.1186/1754-6834-6-15 ID - Pu2013 ER - TY - JOUR AU - Meng, X. AU - Pu, Y. AU - Yoo, C. G. AU - Li, M. AU - Bali, G. AU - Park, D. -. Y. AU - Gjersing, E. AU - Davis, M. AU - Wellington, M. AU - Tuskan, G. PY - 2016 DA - 2016// TI - An in-depth understanding of biomass recalcitrance using natural poplar variants as the feedstock JO - ChemSusChem VL - 10 UR - https://doi.org/10.1002/cssc.201601303 DO - 10.1002/cssc.201601303 ID - Meng2016 ER - TY - JOUR AU - Cao, S. AU - Pu, Y. AU - Studer, M. AU - Wyman, C. AU - Ragauskas, A. J. PY - 2012 DA - 2012// TI - Chemical transformations of Populus trichocarpa during dilute acid pretreatment JO - Rsc Advances VL - 2 UR - https://doi.org/10.1039/c2ra22045h DO - 10.1039/c2ra22045h ID - Cao2012 ER - TY - JOUR AU - Foston, M. B. AU - Hubbell, C. A. AU - Ragauskas, A. J. PY - 2011 DA - 2011// TI - Cellulose isolation methodology for NMR analysis of cellulose ultrastructure JO - Materials VL - 4 UR - https://doi.org/10.3390/ma4111985 DO - 10.3390/ma4111985 ID - Foston2011 ER - TY - JOUR AU - Bali, G. AU - Khunsupat, R. AU - Akinosho, H. AU - Payyavula, R. S. AU - Samuel, R. AU - Tuskan, G. A. AU - Kalluri, U. C. AU - Ragauskas, A. J. PY - 2016 DA - 2016// TI - Characterization of cellulose structure of Populus plants modified in candidate cellulose biosynthesis genes JO - Biomass Bioenergy VL - 94 UR - https://doi.org/10.1016/j.biombioe.2016.08.013 DO - 10.1016/j.biombioe.2016.08.013 ID - Bali2016 ER - TY - JOUR AU - Sun, R. AU - Fang, J. AU - Tomkinson, J. AU - Geng, Z. AU - Liu, J. PY - 2001 DA - 2001// TI - Fractional isolation, physico-chemical characterization and homogeneous esterification of hemicelluloses from fast-growing poplar wood JO - Carbohydr Polym VL - 44 UR - https://doi.org/10.1016/S0144-8617(00)00196-X DO - 10.1016/S0144-8617(00)00196-X ID - Sun2001 ER - TY - JOUR AU - Yuan, T. -. Q. AU - Xu, F. AU - He, J. AU - Sun, R. -. C. PY - 2010 DA - 2010// TI - Structural and physico-chemical characterization of hemicelluloses from ultrasound-assisted extractions of partially delignified fast-growing poplar wood through organic solvent and alkaline solutions JO - Biotechnol Adv VL - 28 UR - https://doi.org/10.1016/j.biotechadv.2010.05.016 DO - 10.1016/j.biotechadv.2010.05.016 ID - Yuan2010 ER - TY - JOUR AU - Capanema, E. A. AU - Balakshin, M. Y. AU - Kadla, J. F. PY - 2005 DA - 2005// TI - Quantitative characterization of a hardwood milled wood lignin by nuclear magnetic resonance spectroscopy JO - J Agric Food Chem VL - 53 UR - https://doi.org/10.1021/jf0515330 DO - 10.1021/jf0515330 ID - Capanema2005 ER - TY - JOUR AU - Yuan, T. -. Q. AU - Sun, S. -. N. AU - Xu, F. AU - Sun, R. -. C. PY - 2011 DA - 2011// TI - Structural characterization of lignin from triploid of Populus tomentosa Carr JO - J Agric Food Chem VL - 59 UR - https://doi.org/10.1021/jf2003865 DO - 10.1021/jf2003865 ID - Yuan2011 ER - TY - JOUR AU - Samuel, R. AU - Pu, Y. AU - Jiang, N. AU - Fu, C. AU - Wang, Z. -. Y. AU - Ragauskas, A. PY - 2014 DA - 2014// TI - Structural characterization of lignin in wild-type versus COMT down-regulated switchgrass JO - Front Energy Res VL - 1 UR - https://doi.org/10.3389/fenrg.2013.00014 DO - 10.3389/fenrg.2013.00014 ID - Samuel2014 ER - TY - JOUR AU - Meng, X. AU - Wells, T. AU - Sun, Q. AU - Huang, F. AU - Ragauskas, A. PY - 2015 DA - 2015// TI - Insights into the effect of dilute acid, hot water or alkaline pretreatment on the cellulose accessible surface area and the overall porosity of Populus JO - Green Chem VL - 17 UR - https://doi.org/10.1039/C5GC00689A DO - 10.1039/C5GC00689A ID - Meng2015 ER - TY - JOUR AU - Adani, F. AU - Papa, G. AU - Schievano, A. AU - Cardinale, G. AU - D’Imporzano, G. AU - Tambone, F. PY - 2010 DA - 2010// TI - Nanoscale structure of the cell wall protecting cellulose from enzyme attack JO - Environ Sci Technol VL - 45 UR - https://doi.org/10.1021/es1020263 DO - 10.1021/es1020263 ID - Adani2010 ER - TY - JOUR AU - Shen, J. AU - Wyman, C. E. PY - 2011 DA - 2011// TI - A novel mechanism and kinetic model to explain enhanced xylose yields from dilute sulfuric acid compared to hydrothermal pretreatment of corn stover JO - Bioresour Technol VL - 102 UR - https://doi.org/10.1016/j.biortech.2011.04.001 DO - 10.1016/j.biortech.2011.04.001 ID - Shen2011 ER - TY - JOUR AU - Kim, Y. AU - Kreke, T. AU - Mosier, N. S. AU - Ladisch, M. R. PY - 2014 DA - 2014// TI - Severity factor coefficients for subcritical liquid hot water pretreatment of hardwood chips JO - Biotechnol Bioeng VL - 111 UR - https://doi.org/10.1002/bit.25009 DO - 10.1002/bit.25009 ID - Kim2014 ER - TY - JOUR AU - Steinbach, D. AU - Kruse, A. AU - Sauer, J. PY - 2017 DA - 2017// TI - Pretreatment technologies of lignocellulosic biomass in water in view of furfural and 5-hydroxymethylfurfural production-a review JO - Biomass Convers Biorefinery VL - 7 UR - https://doi.org/10.1007/s13399-017-0243-0 DO - 10.1007/s13399-017-0243-0 ID - Steinbach2017 ER - TY - JOUR AU - Zhao, X. AU - Zhang, L. AU - Liu, D. PY - 2012 DA - 2012// TI - Biomass recalcitrance. Part I: the chemical compositions and physical structures affecting the enzymatic hydrolysis of lignocellulose JO - Biofuel Bioprod Bior VL - 6 UR - https://doi.org/10.1002/bbb.1331 DO - 10.1002/bbb.1331 ID - Zhao2012 ER - TY - JOUR AU - Li, M. AU - Pu, Y. AU - Yoo, C. G. AU - Gjersing, E. AU - Decker, S. R. AU - Doeppke, C. AU - Shollenberger, T. AU - Tschaplinski, T. J. AU - Engle, N. L. AU - Sykes, R. W. PY - 2017 DA - 2017// TI - Study of traits and recalcitrance reduction of field-grown COMT down-regulated switchgrass JO - Biotechnol Biofuels VL - 10 UR - https://doi.org/10.1186/s13068-016-0695-7 DO - 10.1186/s13068-016-0695-7 ID - Li2017 ER - TY - JOUR AU - Singh, S. AU - Khanna, S. AU - Moholkar, V. S. AU - Goyal, A. PY - 2014 DA - 2014// TI - Screening and optimization of pretreatments for Parthenium hysterophorus as feedstock for alcoholic biofuels JO - Appl Energy VL - 129 UR - https://doi.org/10.1016/j.apenergy.2014.05.008 DO - 10.1016/j.apenergy.2014.05.008 ID - Singh2014 ER - TY - JOUR AU - Hall, M. AU - Bansal, P. AU - Lee, J. H. AU - Realff, M. J. AU - Bommarius, A. S. PY - 2010 DA - 2010// TI - Cellulose crystallinity–a key predictor of the enzymatic hydrolysis rate JO - FEBS J VL - 277 UR - https://doi.org/10.1111/j.1742-4658.2010.07585.x DO - 10.1111/j.1742-4658.2010.07585.x ID - Hall2010 ER - TY - JOUR AU - Nimlos, M. R. AU - Beckham, G. T. AU - Matthews, J. F. AU - Bu, L. AU - Himmel, M. E. AU - Crowley, M. F. PY - 2012 DA - 2012// TI - Binding preferences, surface attachment, diffusivity, and orientation of a family 1 carbohydrate-binding module on cellulose JO - J Biol Chem VL - 287 UR - https://doi.org/10.1074/jbc.M112.358184 DO - 10.1074/jbc.M112.358184 ID - Nimlos2012 ER - TY - JOUR AU - Liu, Y. -. S. AU - Baker, J. O. AU - Zeng, Y. AU - Himmel, M. E. AU - Haas, T. AU - Ding, S. -. Y. PY - 2011 DA - 2011// TI - Cellobiohydrolase hydrolyzes crystalline cellulose on hydrophobic faces JO - J Biol Chem VL - 286 UR - https://doi.org/10.1074/jbc.M110.216556 DO - 10.1074/jbc.M110.216556 ID - Liu2011 ER - TY - STD TI - Mosier NS, Hall P, Ladisch CM, Ladisch MR. Reaction kinetics, molecular action, and mechanisms of cellulolytic proteins. In: Recent Progress in Bioconversion of Lignocellulosics. Springer; 1999: 23-40. ID - ref38 ER - TY - JOUR AU - Leschinsky, M. AU - Zuckerstätter, G. AU - Weber, H. K. AU - Patt, R. AU - Sixta, H. PY - 2008 DA - 2008// TI - Effect of autohydrolysis of Eucalyptus globulus wood on lignin structure. Part 2: influence of autohydrolysis intensity JO - Holzforschung VL - 62 ID - Leschinsky2008 ER - TY - JOUR AU - Samuel, R. AU - Cao, S. AU - Das, B. K. AU - Hu, F. AU - Pu, Y. AU - Ragauskas, A. J. PY - 2013 DA - 2013// TI - Investigation of the fate of poplar lignin during autohydrolysis pretreatment to understand the biomass recalcitrance JO - Rsc Advances VL - 3 UR - https://doi.org/10.1039/c3ra40578h DO - 10.1039/c3ra40578h ID - Samuel2013 ER - TY - JOUR AU - Overend, R. P. AU - Chornet, E. AU - Gascoigne, J. PY - 1987 DA - 1987// TI - Fractionation of lignocellulosics by steam-aqueous pretreatments [and discussion] JO - Philos Trans Royal Soc London VL - 321 UR - https://doi.org/10.1098/rsta.1987.0029 DO - 10.1098/rsta.1987.0029 ID - Overend1987 ER - TY - JOUR AU - Kumar, R. AU - Hu, F. AU - Hubbell, C. A. AU - Ragauskas, A. J. AU - Wyman, C. E. PY - 2013 DA - 2013// TI - Comparison of laboratory delignification methods, their selectivity, and impacts on physiochemical characteristics of cellulosic biomass JO - Biores Technol VL - 130 UR - https://doi.org/10.1016/j.biortech.2012.12.028 DO - 10.1016/j.biortech.2012.12.028 ID - Kumar2013 ER - TY - JOUR AU - Yoo, C. G. AU - Pu, Y. AU - Li, M. AU - Ragauskas, A. J. PY - 2016 DA - 2016// TI - Elucidating structural characteristics of biomass using solution-state 2 D NMR with a mixture of deuterated dimethylsulfoxide and hexamethylphosphoramide JO - Chemsuschem VL - 9 UR - https://doi.org/10.1002/cssc.201600135 DO - 10.1002/cssc.201600135 ID - Yoo2016 ER - TY - JOUR AU - Hu, Z. AU - Yeh, T. -. F. AU - Chang, H. -. m. AU - Matsumoto, Y. AU - Kadla, J. F. PY - 2006 DA - 2006// TI - Elucidation of the structure of cellulolytic enzyme lignin JO - Holzforschung VL - 60 UR - https://doi.org/10.1515/HF.2006.061 DO - 10.1515/HF.2006.061 ID - Hu2006 ER - TY - JOUR AU - Cao, S. AU - Pu, Y. AU - Studer, M. AU - Wyman, C. AU - Ragauskas, A. J. PY - 2012 DA - 2012// TI - Chemical transformations of Populus trichocarpa during dilute acid pretreatment JO - RSC Adv VL - 2 UR - https://doi.org/10.1039/c2ra22045h DO - 10.1039/c2ra22045h ID - Cao2012 ER - TY - JOUR AU - Mansfield, S. D. AU - Kim, H. AU - Lu, F. AU - Ralph, J. PY - 2012 DA - 2012// TI - Whole plant cell wall characterization using solution-state 2D NMR JO - Nat Protoc VL - 7 UR - https://doi.org/10.1038/nprot.2012.064 DO - 10.1038/nprot.2012.064 ID - Mansfield2012 ER - TY - JOUR AU - Kim, H. AU - Ralph, J. PY - 2014 DA - 2014// TI - A gel-state 2D-NMR method for plant cell wall profiling and analysis: a model study with the amorphous cellulose and xylan from ball-milled cotton linters JO - Rsc Advances VL - 4 UR - https://doi.org/10.1039/C3RA46338A DO - 10.1039/C3RA46338A ID - Kim2014 ER - TY - JOUR AU - José, C. AU - Lino, A. G. AU - Colodette, J. L. AU - Lima, C. F. AU - Gutiérrez, A. AU - Martínez, Á. T. AU - Lu, F. AU - Ralph, J. AU - Rencoret, J. PY - 2015 DA - 2015// TI - Differences in the chemical structure of the lignins from sugarcane bagasse and straw JO - Biomass Bioenergy VL - 81 UR - https://doi.org/10.1016/j.biombioe.2015.07.006 DO - 10.1016/j.biombioe.2015.07.006 ID - José2015 ER -