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Table 5 Calculated values for the oxidation Eox, reduction Ered and formal potential Eo’ estimated with cyclic voltammetry and FTacV for lignins immobilized on a glassy carbon electrode with the use of Nafion in 100 mM tartrate buffer pH 5.0 at 50 °C

From: Effect of lignin fractions isolated from different biomass sources on cellulose oxidation by fungal lytic polysaccharide monooxygenases

 

Cyclic Voltammetry

FTacV

E ox

E red

E ox

E red

Eo’

HT-A-WS

387

281

322.3 ± 11.2

320.2 ± 17.9

346.5 ± 21.1

SE-B

361

241

325.7 ± 7.8

306.9 ± 16.5

316.3 ± 18.2

SE-S

359

241

357.1 ± 11.7

339.3 ± 7.2

348.2 ± 13.8

OS-B

358

274

283.3 ± 3.4

337.1 ± 23.3

310.2 ± 23.6

OS-S

368

258

363.7 ± 11.1

352.7 ± 19.8

358.2 ± 22.7

OS-A-B

367

272

310.2 ± 24.1

303.9 ± 9

307.1 ± 33.1

OS-A-S

361

271

347.5 ± 21.5

315.4 ± 27.6

331.4 ± 31.9

OS-B-LF

355

218

269.9 ± 11.9

229.9 ± 19.1

249.9 ± 23.8

OS-S-LF

356

252

349.6 ± 12.5

309.1 ± 32.1

354.7 ± 34.5

OS-A-B-LF

358

223

264.6 ± 34.2

197.0 ± 18.6

230.8 ± 47.9

OS-A-S-LF

353

190

278.4 ± 20.0

209.8 ± 22.7

256.7 ± 30.2