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Table 1 FT-IR analysis of WPC derived from AL, DA, LHW and AFEX pretreatment

From: Understanding the structural characteristics of water-soluble phenolic compounds from four pretreatments of corn stover and their inhibitory effects on enzymatic hydrolysis and fermentation

Wavenumber/cm−1

Origin

Attribution and description of FT-IR absorption

Wavenumber cm−1

AL-WPC

DA-WPC

LHW-WPC

AFEX-WPC

3200–3400

O–H

Wide absorption band, aliphatic and aromatic O–H stretching

3308

3308

3308

3308

3350–3200

CONH2

[36], N–H absorption, double peak

NA

NA

NA

3210 and 3348

2908–2992

CH3, CH2

Aliphatic and aromatic O–H stretching

2925

2925

2925

2939

1650–1660

CONH, CONH2

C=O stretching vibration

NA

NA

NA

1654

1610–1550 and 1420–1300

COO–

Carboxylate

1567 (1410)

1567 (1410)

1567 (1410)

1567 (1410)

1600 (1450)

Ar

Aromatic hydrocarbon

1600 (1450)

1600 (1450)

1600 (1450)

1600 (1450)

1507–1515

 

Aromatic skeletal vibration; G > S

1509

1509

1509

1509

1267

O–, CO–O

G ring and acyl-oxygen bond CO–O stretching vibration

NA

NA

1267

NA

1237–1241

OCH3

Methoxyl, C–C and C–O stretching vibration; C]O stretching vibration (condensed G > etherified G)

1235

NA

1239

1236

1168–1170

COOC

HGS characteristics; conjugated ester-based C=O stretching vibration

NA

NA

NA

1169

1126–1127

C–H, C–O

C–H aromatic-plane bending vibration, characteristics of S ring; coincide with secondary alcohol C–O stretching vibration

1127

1126

1126

1127

1035–1045

C–H, C–O

C–H aromatic in-plane bending vibration, G > S; primary alcohol C–O stretching vibration

1042

NA

1042

1038

834–835

C–H

S ring C–H out-of-plane bending vibration

835

NA

NA

835