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Table 1 GC analysis of pyrolytic aqueous condensate (PAC) treated with overliming at different conditions

From: Detoxification of a pyrolytic aqueous condensate from wheat straw for utilization as substrate in Aspergillus oryzae DSM 1863 cultivations

Substance

A. oryzae growth limit [g/L]a

c in original PAC [g/L]b

c [g/L] in PAC after treatment at 100 °C and the following conditions…

Duration [h]

4

4

1.5

Initial pH

10

10

12

Hydroxide

Ca(OH)2

NaOH

NaOH

Acetate

> 70

29.76

 

40.51 ± 0.19

38.35 ± 0.33

41.24 ± 1.87

Acetol

15

51.46

 

9.99 ± 0.91

11.50 ± 0.75

6.31 ± 0.42

Guaiacol

1

1.80

 

0.55 ± 0.01

0.67 ± 0.01

0.48 ± 0.00

Furfural

0.3

2.94

 

0.22 ± 0.03

0.31 ± 0.06

0.12 ± 0.00

Phenol

0.7

0.64

 

0.44 ± 0.00

0.46 ± 0.01

0.4 ± 0.00

2-Cyclopenten-1-one

0.0625

3.40

 

1.22 ± 0.01

1.11 ± 0.03

0.45 ± 0.00

  1. aDetermined by Dörsam et al. [19] as % (w/v). The concentration was converted into g/L assuming the density of water [2]. The only exception was acetate, for which, according to the results of Kövilein et al. [42], no growth limit was determined so far
  2. bGC/MS analysis performed by Thünen Institute of Wood Research in Hamburg for PAC that was neither pH adjusted nor filtered