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Table 2 Fitted rate constants and activation energies for primary hydrothermal solubilisation reactions of wheat straw

From: The kinetics of inhibitor production resulting from hydrothermal deconstruction of wheat straw studied using a pressurised microwave reactor

Temperature (°C)

Total solubilisation

Hemicellulose solubilisation

Lignin solubilisation

 

ks(min−1)

R2

kh(min−1)

R2

kl(min−1)

R2

180

0.040 (0.012)

0.987

0.040 (0.01)

0.988

0.074 (0.029)

0.974

200

0.221 (0.033)

0.994

0.219 (0.034)

0.990

0.31 (0.055)

0.950

220

0.982 (0.099)

0.999

0.993 (0.105)

0.999

1.12 (0.295)

0.990

Arrhenius analysis

      

Es (kJmol−1)

148 (21, 1.65)

0.999

149 (16, 1.23)

0.998

126 (12, 0.90)

0.999

  1. First or single number in brackets, ±95% confidence limits of parameter estimation; second number in brackets, ± standard error of parameter estimation.