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Table 4 Quantification of the functional groups (mmol/g) by quantitative 31P-NMR in the alkali lignins obtained by the integrated process

From: Synergetic effect of dilute acid and alkali treatments on fractional application of rice straw

Lignin fractions

Aliphatic OH

Syringyl OH

Guaiacyl OH

H + P−OH

Carboxylic group

Total phenolic OH

C

NC

C

NC

AL

2.72

0.02

0.12

0.07

0.35

0.16

0.86

0.72

L(100-0.5-2)

1.56

0.11

0.34

0.20

0.59

0.31

0.93

1.55

L(130-0.5-2)

1.40

0.16

0.34

0.21

0.60

0.35

0.93

1.66

L(150-0.5-2)

1.39

0.17

0.35

0.22

0.60

0.37

1.01

1.71

L(130-0.5-0.5)

1.45

0.11

0.31

0.19

0.57

0.34

0.93

1.52

L(130-0.5-3)

1.39

0.19

0.36

0.22

0.62

0.37

0.97

1.76

L(130-0.25-2)

1.47

0.18

0.32

0.19

0.60

0.32

0.88

1.61

L(130-1-2)

1.37

0.20

0.37

0.26

0.68

0.42

1.06

1.93

  1. C condensed; NC non-condensed; H + P−OH the total content of p-hydroxyphenyl OH and free p-coumaric acid