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Table 2 Structural characteristics of the substrates before and after 2 days of enzymatic hydrolysis

From: Impact of the supramolecular structure of cellulose on the efficiency of enzymatic hydrolysis

Substrate

Physical state

Size

Before hydrolysis

After 2 days of hydrolysis

LFD (nm)

LFAD (nm)

SSA (m 2  g −1 )

DCr (%)

LFD (nm)

LFAD (nm)

SSA (m 2  g −1 )

DCr (%)

Conversion yield (%)

Avicel

Dried powder

Micro (round particles)

4.5 ± 0.1

23.7 ± 1.1

113 ± 5

56 ± 3

4.5 ± 0.1

20.4 ± 0.6

131 ± 4

56 ± 1

30.5 ± 0.2

Cotton

Dried fibres

Milli (in length)

5.8 ± 0.1

29.7 ± 1.2

90 ± 4

65 ± 2

n.d.

n.d.

n.d.

n.d.

2.1 ± 0.4

Cotton + NaOH

Dried fibres

Milli (in length)

6.1 ± 0.1

26.2 ± 0.9

102 ± 4

66 ± 2

n.d.

n.d.

n.d.

n.d.

6.3 ± 1.1

OPHS-ND

Never-dried fibres

Milli (in length)

4.7 ± 0.1

17.5 ± 0.8

153 ± 7

57 ± 1

5.8 ± 0.2

20.1 ± 1.1

132 ± 7

65 ± 3

67.7 ± 0.2

OPHS-D

Dried fibres

Milli (in length)

4.7 ± 0.1

28.3 ± 0.7

94 ± 2

57 ± 1

5.0 ± 0.1

29.5 ± 1.1

90 ± 3

59 ± 2

46.2 ± 5.2

NCC-OPHS-ND

Never-dried particles

Nano (rod-like particles)

5.6 ± 0.2

28.9 ± 1.7

92 ± 5

63 ± 2

5.5 ± 0.2

20.6 ± 1.1

130 ± 7

63 ± 3

90.7 ± 2.1

  1. LFD, lateral fibril dimensions (or fibril thickness); LFAD, lateral fibril aggregate dimensions (or aggregate thickness); SSA, specific surface area; DCr, degree of crystallinity estimated from CP/MAS 13C-NMR measurements; n.d., not determined.