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Table 1 GC–MS analysis of catalytic activities and product distribution profiles of the selected CYP152 peroxygenases towards myristic acid (C14)

From: In vitro oxidative decarboxylation of free fatty acids to terminal alkenes by two new P450 peroxygenases

Enzymes

Conversion (%)

Product distribution (%)

1-tridecene

α-OH–C14

β-OH–C14

CYP-Aa162

60.1 ± 2.1

16.0 ± 1.2

78.9 ± 1.4

5.1 ± 0.6

P450BSβ

62.8 ± 5.0

36.8 ± 3.5

30.0 ± 4.2

33.2 ± 3.5

CYP-Sm46Δ29

73.2 ± 8.9

78.4 ± 2.9

0.4 ± 0.1

21.2 ± 0.9

OleTJE

74.2 ± 2.9

91.8 ± 5.9

0.3 ± 0.1

7.9 ± 1.5