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Table 3 VLE binary interaction parameters of the NRTL and UNIQUAC models for 2,3-butanediol (i) and water (j)

From: Purification of 2,3-butanediol from fermentation broth: process development and techno-economic analysis

Parameter

Thermodynamic model

NRTL

UNIQUAC

a ij

2.43182

0.623312

a ji

− 2.00197

0.0692492

b ij (K)

35.5157

− 123.719

b ji (K)

409.421

− 183.929

c ij

0.3

–

AAD

0.0047

0.0049