Table 4 LLE binary interaction parameters of the NRTL and UNIQUAC models for 2,3-butanediol (2,3-BDO), water, and oleyl alcohol (OA)
System | NRTL | UNIQUAC | |||||||
|---|---|---|---|---|---|---|---|---|---|
a ij | a ji | b ij (K) | b ji (K) | c ij | a ij | a ji | b ij (K) | b ji (K) | |
2,3-BDO/Water | − 0.5863 | 0.567324 | − 107.067 | 899.029 | 0.2 | 7.06203 | − 34.0042 | − 2388.66 | 10,000 |
2,3-BDO/OA | − 31.1741 | 20.1625 | 9998.51 | − 6329.68 | 0.2 | − 1.16437 | − 17.0389 | 2.92684 | 4985.16 |
Water-OA | − 11.9258 | − 28.0351 | 5808.59 | 9999.42 | 0.2 | 0.967516 | − 22.3601 | − 225.248 | − 7369.56 |
AAD | 0.0186 | 0.0211 | |||||||