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Table 1 Comparison of the characteristics of the fast, catalytic and HTL biocrudes

From: Potential yields and emission reductions of biojet fuels produced via hydrotreatment of biocrudes produced through direct thermochemical liquefaction

 

Units

Testing method

Fast pyrolysis biocrude

Catalytic pyrolysis biocrude

Hydrothermal liquefaction biocrude

Density @ 15 °C

kg/m3

ASTM D4052

1198

1163

1169.2a

Specific gravity 60/60F

 

ASTM D4052

1.197

1.164

Elemental analysis

 C

wt%

ASTM D5291

44.1

64.6

70.4

 H

wt%

ASTM D5291

7.5

7.3

7.44

 N

wt%

ASTM D5291b

0.132

0.16

0.12

 S

ppm

ASTM D5453

84

360

1050c

 O (dry basis)

wt%

In-house Elementar

35.6

16.5

14.5

Water content by Karl-Fisher

wt%

ASTM E203

23.5

9.1

8.91

Heat of combustion (net)

MJ/kg

ASTM D240

16.39

26.09

27.40

Total acid number (TAN)

mg KOH/g

ASTM D664

125

82.6

28.6

Kinematic viscosity at 40 °C

cSt

ASTM D445

20.67

236.4

503.4d

Ash content

wt%

ASTM D482

0.013

0.93

0.61

Pyrolysis solids content

wt%

ASTM D7579

0.03

1.32

1.48

pH

pH

In-house

2.66

3.00

4.53e

Flash point

°C

ASTM D93

50.5

< 40.0

Not detectedf

Pour point

°C

ASTM D5460

− 36

− 6

33

Aromaticity by 13C NMR

%

ASTM D5461

42.9

63.9

60.9

Total carbonyl

mol/kg

ASTM E3146

4.5

3.2

Not determined

  1. aDensity @ 28 °C, in-house (Helpyc)
  2. bASTM D5762
  3. cASTM D4294
  4. dKinematic viscosity at 80 °C
  5. epH at 21 °C, ASTM D1293C
  6. fNo flash was detected before the sample began to boil