Fast pyrolysis | Catalytic pyrolysis | HTL | ||||
---|---|---|---|---|---|---|
Canmet | PNNL | Canmet | PNNL | Canmet | PNNL | |
Composition | ||||||
Acidity, total mg KOH/g Max 0.10 | 0.064 | 0.11 | 0.101 | 0.012 | 0.100 | 0.014 |
Aromatics, volume percent Max 25 | 17.7 | 18.6 | 19.3 | 30.4 | 14.1 | 20.9 |
Sulfur, mercaptan, mass percent Max 0.003 | 0.0019 | < 0.0003 | 0.0003 | 0.0021 | Nd | < 0.0003 |
Sulfur, total mass percent Max 0.30 | < 0.25 | < 0.25 | 0.0518 | < 0.25 | ||
Volatility | ||||||
Flash point, °C Min 38 | 61 | 43 | 58.5 | 34.5 | 59.0 | 34.5 |
Density at 15 °C, kg/m3 775 to 840 | 818.9 | 843.4 | 827.8 | 852.6 | 829.0 | 853 |
Fluidity | ||||||
Freezing point, °C Max − 47 Jet A-1I | − 57.6 | − 46.7 | − 58.3 | < − 80 | − 45 | − 84 |
Viscosity − 20 °C, mm2/s, Max 8.0 | 5.164 | 5.176 | 5.306 | 3.499 | 6.6 | 4.431 |
Combustion | ||||||
Net heat of combustion, MJ/kg Min 42.8 | 42.92 | 42.245 | 42.32 | 42.477 | 42.85 | 42.55 |
One of the following requirements shall be met: (1) Smoke point, mm, or Min 25.0 (2) Smoke point, mm, Min 18.0 and naphthalenes, volume, percent Max 3.0 | 21 | 18.3 | 20 | 14.3 | 19.7 | 17 |
0.51 | 2.17 | 1.51 | 0.36 | 1.07 | 0.44 | |
Corrosion | ||||||
Copper strip, 2 h at 100 °C Max No. 1 (3 is off spec) | 1b | 1a | 3a | 3b | 1a | 3a |
Contaminants | ||||||
Existent gum, mg/100 ml Max 7 | 15 | 28 | 65 | < 1 | 41 | 3 |
Nitrogen, mg/kg Max 2 | 270 | 9.7 | < 0.15 | 81 | ||
Water, mg/kg Max 75 | 138 | 440 | 159 | 66 | 79 | 74 |
Sulfur, mg/kg Max 15 | 480 | 11 | 423 | 39.3 | 0.0518 | |
Oxygen wt% | 0.3 | 1.08 | 1.18 | < 0.01 | 2.42 | 0.13 |