Table 2 (Bio)processing of vinylphenols into valuable compounds
Substrate 1a | Catalyst | Product 1/Substrate 2 | Catalyst | Product 2 | References |
|---|---|---|---|---|---|
– | – | 4-VG | Engineered E. coli | Vanillin | Saito et al. [115] |
– | – | 4-VP | Engineered E. coli | (S)-4-(1-hydroxyethyl)phenol | Wuensch et al. [116] |
– | – | 4-VP | L. plantarum reductase | 4-ethylphenol | Santamaria et al. [114] |
– | – | 4-VG | L. plantarum reductase | 4-ethylguaiacol | Santamaria et al. [114] |
CafA | L. plantarum PAD | 4-VC | L. plantarum reductase | 4-ethylcatechol | Santamaria et al. [114] |
FA | M. colombiense PAD | 4-VG | Pd/C | 4-ethylguaiacol | Pesci et al. [117] |
SA (canola) | B. pumilus PAD | 4-VS (canolol) | AIBN or BF3·(Et2O)2 | Poly-vinylsyringol | Morley et al. [86] |
pCA + FA (corn bran) | B. pumilus PAD | 4-VP 4-VG | BF3·(Et2O)2 | Poly-(vinylguaiacol-co-vinylphenol) | Leisch et al. [91] |
pCA, FA (plant biomasses) | B. subtilis PAD | 4-VP 4-VG | T. versicolor laccase | Homo- and co-polymers | Williamson et al. [99] |